RHEOLOGICAL PROPERTIES OF CHITOSAN EDIBLE FILMS

  • Gabor Ivan Zsivanovits Scientic secretary of Institute of Food Preservation and Quality Email: g.zsivanovits@canri.org
  • Maria Georgieva Marudova Paisii Hilendarski University of Plovdiv Email: margo@uni-plovdiv.bg
Keywords: edible film, composite film, chitosan, essential oils, grape seed oil, hydrophilic properties, rheology

Abstract

e increased requirements for high quality and extended shelf life of fresh and  minimally processed fruits in the recent years has helped forward the development of some innovative  techniques to keep the natural and fresh look of the food for as long as possible while ensuring it’s  safety. In this context formulation of new composite edible coating is a promising way to ensure fruit  quality for a longer period. In this study hydrophilic and mechanical properties of composite edible lms from chitosan  and grape seed oil have been determined. Due to its biocompatibility, nontoxicity and antibacterial  activity, chitosan is a preferred polysaccharide for the production of edible lms and coatings.  Grapeseed oil is high in vitamin E and phenolic antioxidants. It is also a rich source of omega-6  polyunsaturated fats. Mechanical experiments of the edible lms were done in tensile mode at constant deformation  rate using the LS 1 (Lloyd Instruments) Universal Testing Machine. e break point, mechanical  losses and relaxation parameters were determined. It was found that the increase of the grape seed oil content reduces the water holding capacity of the edible Ęlms, hence their hydrophobic properties are enhanced. At the same time the oil addition reduces the Ęlm strength and they become more brittle. Adding oil at concentrations up to 2 % results in an increase in the Young’s modulus. At higher concentration a decrease of the Young’s modulus is noticed. When the oil content increases, it plays a role of plasticizer, which enhances the viscosity properties of the material. As a result of the plasticizing eĭect of the oil, the stress and the relative deformation at rupture decrease, the equilibrium stress values decrease aNer the relaxation process, therefore, the visco-elastic behaviour with full relaxation of the tension is increased. Ɗe broadness of the relaxation time spectrum decreases when the oil content increases.

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References

Guilbert S., Gontard N., and Cuq B. (1995). Technology and applications of edible protective lms. Packag. Technol. Sci., 8:339–346.

Report from the commission to the European parliament and the council on the progress of the re-evaluation of food additives {sec (2007) 998}; https://www.parliament.bg/pub/ECD/69864COM_2007_418_EN_ACTE_f.pdf

FDA. (2006). Food additives permitted for direct addition to food for human consumption 21CFR172, subpart C. Coatings, lms and related substances. https://www.fda.gov/Food/GuidanceRegulation/GuidanceDocumentsRegulatoryInformation/IngredientsAdditivesGRASPackaging/ucm073015.htm

Han J. H. (2002). Protein-based edible films and coatings carrying antimicrobial agents. In: Gennadios, A. Ed. Protein-based lms and coatings. Boca Raton: CRC Press, 485–499.

Vargas M., Pastor C., Chiralt A., Julian D. Mcclements, and Ch. G. Lez-Martinez, 2008. Recent Advances in Edible Coatings for Fresh and Minimally Processed Fruits; Critical Reviews in Food Science and Nutrition; Volume 48, Issue 6, 2008

Min S., and Krochta J. M. (2005). Antimicrobial lms and coatings for fresh fruit and vegetables. In: Jongen, W. Ed. Improving the safety of fresh fruit and vegetables. New York: CRC Press, 354–492.

Marudova M., Delcheva E. and Zsivanovits G. (2014): Mechanical Properties of Composite Films Based on Chitosan and Poly (L-lactic acid); Bulgarian Chemical Communications Volume 47, Special Issue B 2015 127–134.

Altiok D. & Altiok E. & Tihminlioglu, F. (2010). Physical, antibacterial and antioxidant properties of chitosan lms incorporated with thyme oil for potential wound healing applications. Journal of materials science. Materials in medicine. 21. 2227–36. 10.1007/s10856–010–4065-x.

Weiss J., Takhistov P., and McClements D. J. (2006). Functional materials in food nanotechnology. J. Food Sci., 71:107–116.

Bravin B., Peressini D., and Sensidoni A. (2004). In,uence of emulsier type and content on functional properties of polysaccharide lipid-based edible lms. J. Agric. Food Chem., 52:6648–6455.

ASTM (2013). Standard test methods for water vapor transmission of materials. Standard Designations: E96–95. In: Annual Book of ASTM, Philadelphia: ASTM, 406–413.

Zsivanovits G., & Marudova-Zsivanovits M. (2009). Rheological properties of pectin-polycation crosslinked lms. Journal of Optoelectronics and Advanced Materials, 11 (10), 1416.

Vozбry E., Csima G., Csapу L., & Mohos F. Application of Fractional Calculus in Food Rheology. Journal of Food Physics Vol. XXVIII. — XXIX. pp 26–32

Csima, G., & Vozбry, E. (2016). Stretched exponent rheological model of gum candy. Acta Alimentaria, 45 (1), 149–156.

Modulus of Elasticity — Young Modulus for some common Materials http://www.bestech.com.au/wp-content/uploads /Modulus-of-Elasticity.pdf

Published
2019-09-30
How to Cite
Zsivanovits G. I., Marudova M. G. RHEOLOGICAL PROPERTIES OF CHITOSAN EDIBLE FILMS // Health, physical culture and sports, 2019, № 4(15). P. 220-227. URL: http://hpcas.ru/article/view/7100.
Section
MEDICAL AND BIOLOGICAL PROBLEMS OF HUMAN HEALTH
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